Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant.

نویسندگان

  • Daqian Xu
  • Shoufeng Wang
  • Zhiqiang Shen
  • Chungu Xia
  • Wei Sun
چکیده

We demonstrate an efficient enantioselective oxidation of secondary alcohols catalyzed by Mn(III)-salen complex using N-bromosuccinimide (NBS) as the oxidant. The new protocol is very efficient for the oxidative kinetic resolution of a variety of secondary alcohols, including ortho-substituted benzylic alcohols.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 10 14  شماره 

صفحات  -

تاریخ انتشار 2012